I am unaware of any coating you can coat metal and heat-weld the membrane to it. You have a few options to do this if you want to use aluminum as your cover metal:
Fabricate a cleat from TPO-coated metal with a raised edge that you can weld the membrane on, then snap the aluminum as a fascia piece.
Use TPO cover tape to seal the edge flange into the TPO membrane.
Purchase a prefabricated metal edge that integrates with a TPO system and aluminum edge metal.
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